Abstract
This work is a first assessment of the radiation tolerance of the nanolayered ternary carbides (MAX phases), Zr3AlC2, Nb4AlC3 and (Zr0.5,Ti0.5)3AlC2, using proton irradiation followed by post-irradiation examination based primarily on x-ray diffraction analysis. These specific MAX phase compounds are being evaluated as candidate coating materials for fuel cladding applications in advanced nuclear reactor systems. The aim of using a MAX phase coating is to protect the substrate fuel cladding material from corrosion damage during its exposure to the primary coolant. Proton irradiation was used in this study as a surrogate for neutron irradiation in order to introduce radiation damage into these ceramics at reactor-relevant temperatures. The post-irradiation examination of these materials revealed that the Zr-based 312-MAX phases, Zr3AlC2 and (Zr0.5,Ti0.5)3AlC2 have a superior ability for defect-recovery above 400 °C, whilst the Nb4AlC3 does not demonstrate any appreciable defect recovery below 600 °C. Density functional theory calculations have demonstrated that the structural differences between the 312 and 413-MAX phase structures govern the variation of the irradiation tolerance of these materials.
Details
Original language | English |
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Article number | 183 |
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Number of pages | 12 |
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Journal | Acta Materialia |
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Volume | 183 |
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DOIs | |
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Publication status | Published - 7 Nov 2019 |
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